Baccarat

While its name might suggest a game of extreme sophistication, mystique and allure, it’s actually very simple. Each player, including the one dealing, may bet on either "player" or "house." Two hands are then dealt for both of these, and the game plays out.

Not to mention, this is one game that is known for its extremely generous payouts (and equally large losses). Besides, James Bond's been known to play this game--when he's not playing poker, that is.

-Picture courtesy Thinsktock-